@Incase-1231 Thanks for posting in our Q&A.
Currently, only this request can get the Primary User.
GET /beta/deviceManagement/managedDevices/{managedDeviceId}/users
Additionally, please try to refer to the following link that get all devices and primary users.
https://github.com/microsoftgraph/powershell-intune-samples/blob/master/ManagedDevices/Win10_PrimaryUser_Get.ps1
Not sure if there is a plan to add the email address of the device's Primary User to the query you want. If you are interested in this, it is suggested to post in intune feedback portal. It is a place to collect customers' requirements and problems. Here is the link:
https://feedbackportal.microsoft.com/feedback/forum/ef1d6d38-fd1b-ec11-b6e7-0022481f8472
Hope it will occur in the future.
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