Hi @Max ,
The ability for Outlook clients to use and reserve aliases was added in February 2022.
You could refer to the following command to enable this feature for Exchange online mailboxes.
Set-OrganizationConfig - SendFromAliasEnabled $true
Note: This feature is in preview and not yet generally available. Admins should test and fully understand the client impact and known issues before enabling this feature in your tenant.
For more details on this feature, please refer to this link:
Sending From Email Aliases – Public Preview - Microsoft Community Hub
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