HI,
Basic SKU Load Balancer restricts you to having backend with single VM, or VMs in same availability set, or VMs in VM Scale Set. So from your description you have an existing backend with single VM not in an availability set, so you can't add a new one to the backend.
One option would be to re-create things so you have two VMs in same availability set for your backend pool.
Azure Load Balancer SKUs - SKU comparison
https://video2.skills-academy.com/en-us/azure/load-balancer/skus#skus
Please click Accept Answer if the above was helpful. If you have a question please add a comment.
Thanks.
-TP