@Debashis Jena To allow your Azure App Service to access Azure Blob Storage, you need to enable a firewall exception on the VNet to allow connections from trusted Azure services.
To configure the exception in the Azure portal for Azure Blob Storage, navigate to Networking > Firewalls and virtual networks. Then select Allow Azure services on the trusted services list to access this storage account.
Also, make sure that your WAF is configured to allow traffic to and from Azure Blob Storage. You can deploy Azure Web Application Firewall (WAF) in front of public-facing web applications for additional inspection of incoming traffic. WAF provides centralized protection of your web applications from common exploits and vulnerabilities such as SQL injections, Cross-Site Scripting, local and remote file executions. You can also restrict access to your web applications by countries, IP address ranges, and other http(s) parameters via custom rules.