Hello,
SQL Always On is supported, except in cases where configuration is done on multi subnets.
To resolve this issue, it is recommended to set the network name of the availability group listener to only register a single active IP address in DNS and configure the cluster to use a low TTL value for the registered DNS record. These settings allow for quicker recovery and resolution of the cluster name with the new IP address when failover to a node in a different subnet occurs.
Regarding the MultiSubnetFailover, there is no information indicates whether it is supported in Orchestrator 2022.