Hi @muhi-entra
Thank you for post!
The email field is a different attribute that can be modified without affecting the legacy DN value, so updating the email field does not cause the legacy DN value to change.
The Sync option allows the on-premises Active Directory objects to match the Entra ID Directory Objects Sync option and the legacy DN value are independent of each other and do not affect each other so toggling the Sync option does not effect the legacy DN value to change.
The other side receiving an NDR when sending an email to user could you please share the NDR message for the error code and the reason for the failure. Also let us know is the legacy DN value is change manually?