Something like this:
Import-Csv |
ForEach-Object{
$e = Get-ADUser -filter "employeeno = '$_.'EMPLOYEE NO'"
if ($e){
$e | Set-ADUser -EmployeeID $_.'NameOfEmployeeIDColumnInCSV'
}
}
I don't see anything in the CSV that can be used as an Identity in the Get-ADUser, so I used a filter and "employeeno" as the AD property name -- you should verify that it's the correct property name. If there's a column in your spreadsheet that has can be used as a unique Identity (distinguished name, objectGUID, objectSid, or saMAccountName) then you should eliminate the need for the Get-ADUser and just use a Set-ADUser with the "-Identity" parameter.