We're going to need more information here.
- Did you create the sproc in your SQL database? If not then there is nothing to select in SSRS.
- Can you run the sproc in SQL directly? If not then it won't work in SSRS either.
- Does the sproc have any parameters that are complex (e.g. UDTs)? If so then you might not be able to call it in SSRS.
- In the designer are you connecting to the correct DB that has the sproc and did you restart the designer? It is likely the designer is caching the sprocs.
- Have you confirmed that the sproc is in the right database and that you have permissions to view and call it from the user account that you're connecting as in the designer?
- What version of SQL Server, SSRS and the Report Designer are you using?
- Do other sprocs show up?