psexec syntax error within VB macro.

Try the next statement:

Shell("psexec -i -s -d \REMOTECOMPUTERNAME -u USER -p PASSWORD ""C:\Program Files\LightBurn\LightBurn.exe"" """ & out_file & """", vbNormalFocus)

Thanks Viorel-1

still getting the same compile error: Expected list separator or ).

This is a macro within CorelDraw (CorelDraw have a VB editor for Macros). Basically it will copy the selection in coreldraw and open it in another program LightBurn.
The script work well when both programs are on the same PC. using the code:
Call Shell("C:\Program Files\LightBurn\LightBurn.exe " & """" & out_file & """", vbNormalFocus)

I am trying to open the program LightBurn on another machine on the local network using psexec
(typing directly in CMD window: psexec -i -s -d \REMOTECOMPUTERNAME -u USER -p PASSWORD “C:\Program Files\LightBurn\LightBurn.exe
will do it.

Enclosed bellow is the original code that work when both programs on the same machine:

Sub removeDup()
'variables
Dim sr As ShapeRange
Dim srKeep As New ShapeRange
Dim dupFound As Boolean

Dim shape As shape
Dim keepShape As shape

'set variables
Set sr = ActivePage.Shapes.FindShapes()

For Each shape In sr.Shapes
    dupFound = False
    If srKeep.Count > 0 Then
        For Each keepShape In srKeep.Shapes
             If keepShape.PositionX = shape.PositionX Then
                     If keepShape.PositionY = shape.PositionY Then
                             If keepShape.SizeHeight = shape.SizeHeight Then
                                     If keepShape.SizeWidth = shape.SizeWidth Then
                                             sr.DeleteItem (sr.IndexOf(shape))
                                             dupFound = True
                                             Exit For
                                     End If
                             End If
                     End If
             End If
        Next keepShape
        If Not dupFound Then
             srKeep.Add shape
             dupFound = False
        End If
    Else
        srKeep.Add shape
    End If
Next shape

End Sub
Sub Lightburn()
Dim answer As Integer
Dim OrigSelection As ShapeRange
Set OrigSelection = ActiveSelectionRange
OrigSelection.CreateSelection
Dim expopt As StructExportOptions
Set expopt = CreateStructExportOptions
expopt.UseColorProfile = True
Dim expflt As ExportFilter

Dim out_file As String
out_file = "C:" & Environ("HOMEPATH") & "\export.ai"
If Len(Dir$(out_file)) > 0 Then
    Kill (out_file)
End If

' is an item selected?
If ActiveSelectionRange.Count > 0 Then
    ' something is selected export it
    Set expflt = ActiveDocument.ExportEx(out_file, cdrAI, cdrSelection, expopt)
    With expflt
        .Version = 10 ' FilterAILib.aiVersionCS6
        .TextAsCurves = True
        .PreserveTransparency = True
        .ConvertSpotColors = True
        .SimulateOutlines = False
        .SimulateFills = False
        .IncludePlacedImages = True
        .IncludePreview = True
        .EmbedColorProfile = True
        .Finish
    End With

Else
    answer = MsgBox("Nothing was selected, Export All?", vbYesNo + vbQuestion, "Export All")
    If answer = vbYes Then
        ' Export everything
        Set expflt = ActiveDocument.ExportEx(out_file, cdrAI, cdrAllPages, expopt)
        With expflt
            .Version = 10 ' FilterAILib.aiVersionCS6
            .TextAsCurves = True
            .PreserveTransparency = True
            .ConvertSpotColors = False
            .SimulateOutlines = False
            .SimulateFills = False
            .IncludePlacedImages = True
            .IncludePreview = True
            .EmbedColorProfile = True
            .Finish
        End With

    Else
        'do nothing
        Exit Sub
    End If
End If

' Edit this like if lightburn is in a diffrent location
Call Shell("C:\Program Files\LightBurn\LightBurn.exe " & """" & out_file & """", vbNormalFocus)

End Sub

when I change the path of the file on the local machine to the psexec command, I get the syyntax error.