Hi,
What account are you referring to? If you mean your Microsoft account, then I'm afraid that it is no longer possible to do, see:
Linking Microsoft accounts
https://support.microsoft.com/en-us/account-billing/linking-microsoft-accounts-4044c1bc-f436-60eb-9f6d-2bf64a7cc47f
What you could do instead is to create an alias and logon with that alias:
https://support.microsoft.com/en-us/help/12407/microsoft-account-change-email-phone-number
If it's Microsoft Learning accounts, you may ask for further assistance over at the dedicated Certification Profile - Account Linking forum over here:
https://trainingsupport.microsoft.com/en-us/mcp/forum/mcp_prof-mcp_link
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, thank you!
Best regards,
Leon