You should be able to grab all the current outbound addresses for your App Service via command line or the portal. See https://video2.skills-academy.com/en-us/azure/app-service/overview-inbound-outbound-ips#find-outbound-ips for more information.
Current outbound IP address of App Service
PATRICIA FUENTES
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Hi team,
is any way to know which of all outbound ip addresses is currently being used in runtime in an app service?
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Vivek Kosare 1 Reputation point
2022-03-11T16:44:00.617+00:00 You can check the list of outbound IP addresses in the Properties section of Azure App service on Azure portal (where your app service is published)
OR you can use this azure cli command : az webapp show --resource-group <group_name> --name <app_name> --query outboundIpAddresses --output tsv